[发明专利]含有羟苯基丙酮酸盐双加氧酶抑制剂类的除草剂的增效除草组合物

摘要

本发明公开了一种除草组合物,包括A)至少一种羟苯基丙酮酸盐双加氧酶抑制剂类化合物以及B)选自下组的至少一种化合物,B－a)可选择性防除谷类作物中的单子叶和/或双子叶有害植物的除草剂,B－b)可选择性防除玉米中的单子叶和/或双子叶有害植物的除草剂,B－c)可选择性防除水稻中的单子叶和/或双子叶有害植物的除草剂,B－d)在未耕作土地上不具选择活性除草剂和/或可选择性防除转基因作物中的单子叶和/或双子叶有害植物的除草剂。上述组合物的活性超出单独施用时各除草剂的活性。

主权项

1.一种除草组合物，其中包括有效量的A)至少一种式(I)化合物及其农业上常用的盐(组分A)其中X是基团X1，X2或X3Q是基团Q1，Q2，Q3，Q4或Q5Z是基团Z1，CH2-Z1或Z2；z1是通过碳或氮连接的，五至十元单环或双环的，饱和的，部分饱和的，全部不饱和的或芳族的环，并且该环，除了碳原子外，还含有1，2，3或4个选自氧，硫和氮的杂原子，以及该环是未取代的或被卤素，氰基，硝基，氰基-(C1-C4)-烷基，CO-R15，(C1-C4)-烷基，卤代-(C1-C4)-烷基，(C3-C8)-环烷基，(C1-C4)-烷氧基，卤代-(C1-C4)-烷氧基，(C1-C4)-烷硫基，卤代-(C1-C4)-烷硫基，二-(C1-C4)-烷氨基，苯基或桥氧基一-或多取代，其中所述苯基是未取代的或被卤素，氰基，硝基，(C1-C4)-烷基或卤代-(C1-C4)-烷基一-或多取代；Z2是(C3-C12)-环烷氧基-(C1-C4)-烷基，芳氧基-(C1-C4)-烷基，杂芳氧基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基，卤代-(C1-C4)-烷氧基-(C1-C4)-烷基，芳基-(C1-C4)-烷氧基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷氧基-(C1-C4)-烷基，杂环基-(C1-C4)-烷氧基-(C1-C4)-烷基，芳基-(C3-C8)-环烷硫基-(C1-C4)-烷基，杂芳基-(C3-C8)-环烷硫基-(C1-C4)-烷基，杂环基-(C3-C8)-环烷硫基-(C1-C4)-烷基，(C3-C8)-环烷基亚磺酰基-(C1-C4)-烷基，(C3-C8)-环烷基磺酰基-(C1-C4)-烷基，(C3-C8)-环烷氨基-(C1-C4)-烷基，(C3-C8)-环烷基磺酰氧基-(C1-C4)-烷基，(C3-C8)-环烷基磺酰氨基-(C1-C4)-烷基，(C3-C8)-环烷基羰基-(C1-C4)-烷基，(C3-C8)-环烷基羰氧基-(C1-C4)-烷基，(C3-C8)-环烷氧基羰基-(C1-C4)-烷基，(C3-C8)-环烷基羰基氨基-(C1-C4)-烷基，(C3-C8)-环烷基氨基羰基-(C1-C4)-烷基，(C4-C12)-环烷基-(C1-C4)-烷基，(C4-C12)-环烷硫基-(C1-C4)-烷基，(C4-C12)-环烷基亚磺酰基-(C1-C4)-烷基，(C4-C12)-环烷基磺酰基-(C1-C4)-烷基，(C4-C12)-环烷基氨基-(C1-C4)-烷基，(C4-C12)-环烷基磺酰氧基-(C1-C4)-烷基，(C4-C12)-环烷基磺酰氨基-(C1-C4)-烷基，(C4-C12)-环烷基羰基-(C1-C4)-烷基，(C4-C12)-环烷基羰氧基-(C1-C4)-烷基，(C4-C12)-环烷氧基羰基-(C1-C4)-烷基，(C4-C12)-环烷基羰基氨基-(C1-C4)-烷基，(C4-C12)-环烷氨基羰基-(C1-C4)-烷基，芳硫基-(C1-C4)-烷基，芳基亚磺酰基-(C1-C4)-烷基，芳基磺酰基-(C1-C4)-烷基，芳基氨基-(C1-C4)-烷基，芳基磺酰氧基-(C1-C4)-烷基，芳基磺酰氨基-(C1-C4)-烷基，芳基羰基-(C1-C4)-烷基，芳基羰氧基-(C1-C4)-烷基，芳氧基羰基-(C1-C4)-烷基，芳基羰基氨基-(C1-C4)-烷基，芳基氨基羰基-(C1-C4)-烷基，杂芳硫基-(C1-C4)-烷基，杂芳基亚磺酰基-(C1-C4)-烷基，杂芳基磺酰基-(C1-C4)-烷基，杂芳基氨基-(C1-C4)-烷基，杂芳基磺酰氧基-(C1-C4)-烷基，杂芳基磺酰氨基-(C1-C4)-烷基，杂芳基羰基-(C1-C4)-烷基，杂芳基羰氧基-(C1-C4)-烷基，杂芳氧基羰基-(C1-C4)-烷基，杂芳基羰基氨基-(C1-C4)-烷基，杂芳基氨基羰基-(C1-C4)-烷基，杂环硫基-(C1-C4)-烷基，杂环基亚磺酰基-(C1-C4)-烷基，杂环基磺酰基-(C1-C4)-烷基，杂环基氨基-(C1-C4)-烷基，杂环基磺酰氧基-(C1-C4)-烷基，杂环基磺酰氨基-(C1-C4)-烷基，杂环基羰基-(C1-C4)-烷基，杂环基羰氧基-(C1-C4)-烷基，杂环氧基羰基-(C1-C4)-烷基，杂环基羰基氨基-(C1-C4)-烷基，杂环基氨基羰基-(C1-C4)-烷基，卤代-(C1-C4)-烷硫基-(C1-C4)-烷基，卤代-(C1-C4)-烷基亚磺酰基-(C1-C4)-烷基，卤代-(C1-C4)-烷基磺酰基-(C1-C4)-烷基，卤代-(C1-C4)-烷基氨基-(C1-C4)-烷基，卤代-(C1-C4)-烷基磺酰氧基-(C1-C4)-烷基，卤代-(C1-C4)-烷基磺酰氨基-(C1-C4)-烷基，卤代-(C1-C4)-烷基羰基-(C1-C4)-烷基，卤代-(C1-C4)-烷基羰氧基-(C1-C4)-烷基，卤代-(C1-C4)-烷氧基羰基-(C1-C4)-烷基，卤代-(C1-C4)-烷基羰基氨基-(C1-C4)-烷基，卤代-(C1-C4)-烷基氨基羰基-(C1-C4)-烷基，芳基-(C1-C4)-烷硫基-(C1-C4)-烷基，芳基-(C1-C4)-烷基亚磺酰基-(C1-C4)-烷基，芳基-(C1-C4)-烷基磺酰基-(C1-C4)-烷基，芳基-(C1-C4)-烷基氨基-(C1-C4)-烷基，芳基-(C1-C4)-烷基磺酰氧基-(C1-C4)-烷基，芳基-(C1-C4)-烷基磺酰氨基-(C1-C4)-烷基，芳基-(C1-C4)-烷基羰基-(C1-C4)-烷基，芳基-(C1-C4)-烷基羰氧基-(C1-C4)-烷基，芳基-(C1-C4)-烷氧基羰基-(C1-C4)-烷基，芳基-(C1-C4)-烷基羰基氨基-(C1-C4)-烷基，芳基-(C1-C4)-烷基氨基羰基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷硫基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基亚磺酰基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基磺酰基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基氨基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基磺酰氧基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基磺酰氨基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基羰基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基羰氧基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷氧基羰基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基羰基氨基-(C1-C4)-烷基，杂芳基-(C1-C4)-烷基氨基羰基-(C1-C4)-烷基，杂环基-(C1-C4)-烷硫基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基亚磺酰基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基磺酰基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基氨基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基磺酰氧基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基磺酰氨基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基羰基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基羰氧基-(C1-C4)-烷基，杂环基-(C1-C4)-烷氧基羰基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基羰基氨基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基羰基氨基-(C1-C4)-烷基，杂环基-(C1-C4)-烷基氨基羰基-(C1-C4)-烷基，或O-(CH2)p-O-(CH2)w-R20；W是基团W1，W2，W3或W4之一Y是O或NR26；E与它们连接的两个碳原子一起构成苯环或5-或6-元杂环，其中所述杂环可以是饱和的，部分饱和的，全部不饱和的或芳族的环并且含有1，2或3个选自氧，硫和氮的杂原子，其中该杂环含有至多2个硫或2个氧原子以及含有基团E的苯环或杂环是未取代的或被(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C1-C6)-烷氧基，卤代-(C1-C6)-烷氧基，(C1-C6)-烷硫基，卤代-(C1-C6)-烷硫基，(C1-C6)-烷基亚磺酰基，卤代-(C1-C6)-烷基亚磺酰基，(C1-C6)-烷基磺酰基，卤代-(C1-C6)-烷基磺酰基，氨基磺酰基，(C1-C6)-烷基氨基磺酰基，(C2-C12)-二烷基氨基磺酰基，NR26R27，(C2-C6)-烷氧基烷基，(C2-C6)-烷氧基羰基，(C2-C6)-烷基羰基，卤素，氰基，硝基或吡啶基一-或多取代；R1是卤素，氰基，硝基，(Y)n-S(O)q-R28，(Y)n-CO-R15或代表被v个卤素原子或k个(C1-C4)-烷氧基取代的(C1-C6)-烷基，(C2-C6)-链烯基，(C2-C6)-炔基或(C1-C4)-烷氧基；R2，R3，R5和R7各自独立地代表氢或(C1-C6)-烷基；R4是氢，或代表被k个选自卤素，(C1-C6)-烷硫基和(C1-C6)-烷氧基的基团取代的(C1-C6)-烷基，(C3-C6)-环烷基，四氢吡喃-3-基，四氢吡喃-4-基或四氢噻喃-3-基；R6是氢，(C1-C6)-烷基或CO2R15，或R4和R6一起形成键或三-至六元碳环；R8是OR29，硫代，(C1-C6)-烷硫基，卤代-(C1-C6)-烷硫基，(C1-C6)-烷基亚磺酰基，卤代-(C1-C6)-烷基亚磺酰基，(C1-C6)-烷基磺酰基，卤代-(C1-C6)-烷基磺酰基，卤素，NR26R27，苯硫基，苯基磺酰基或苯基羰基甲硫基，其中最后所述三个取代基被k个选自(C1-C3)-烷基，卤素，氰基和硝基的基团取代；R9是氢，(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C2-C6)-链烯基，(C2-C6)-炔基，CH2CH2OR30或代表苯基或苄基，其中在苯环上被k个选自(C1-C3)-烷基，卤素，氰基和硝基的基团取代；R10是氢，(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C1-C6)-烷氧基，卤代-(C1-C6)-烷氧基，卤素，氰基或硝基；R11是氢，(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C3-C6)-环烷基或卤代-(C3-C6)-环烷基；R12是氢，(C2-C6)-烷氧基羰基，卤代-(C2-C6)-烷氧基羰基，S(O)qR28，CO2H或氰基；R13是(C1-C6)-烷基，卤代-(C1-C6)-烷基，卤代-(C3-C6)-环烷基或代表被基团(C1-C3)-烷基取代的(C3-C6)-环烷基；R14是氰基，(C2-C6)-烷氧基羰基，(C2-C6)-烷基羰基，S(O)q-R30或C(O)NR26R27；R15是(C1-C4)-烷基，卤代-(C1-C4)-烷基或NR26R27；R16和R17各自独立地代表被k个选自卤素，氰基，硝基，(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C1-C6)-烷氧基和卤代-(C1-C6)-烷氧基的基团取代(C1-C6)-烷基，(C2-C6)-链烯基，(C2-C6)-炔基，卤代-(C1-C6)-烷基，芳基或芳基-(C1-C6)-烷基；R18和R19各自独立地代表氢或R16，或R18和R19一起形成(C2-C5)-链烯基链；R20是(C1-C4)-烷基，(C2-C8)-链烯基，(C2-C6)-炔基，卤代-(C1-C6)-烷基，卤代-(C2-C6)-链烯基，卤代-(C2-C6)-炔基，(C1-C6)-烷氧基，(C2-C6)-链烯氧基，(C2-C6)-炔氧基，卤代-(C1-C6)-烷氧基，卤代-(C2-C6)-链烯氧基或卤代-(C2-C6)-炔氧基；R21是氢，(C1-C4)-烷基，卤代-(C1-C4)-烷基，Z1，O-Z1，S-Z1或NR30Z1；R22是氢，(C1-C4)-烷基，(C2-C4)-链烯基或(C2-C4)-炔基，或R21，R22与它们所连接的碳原子一起形成羰基或被q个(C1-C3)-烷基取代的O-CH2CH2-O基团，或R21是氢和R22是Z1；R23和R24各自独立地是(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C3-C6)-环烷基，(C2-C6)-链烯基，卤代-(C2-C6)-链烯基，(C2-C6)-炔基，卤代-(C2-C6)-炔基或Z1；R25是Z1；R26是氢或(C1-C6)-烷基；R27是氢，(C1-C6)-烷基或(C1-C6)-烷氧基，或R26和R27一起形成(CH2)2，(CH2)3，(CH2)4，(CH2)5，或(CH2)2O(CH2)2；R28是(C1-C4)-烷基，卤代-(C1-C4)-烷基或NR26R27；R29是氢，(C1-C6)-烷基，卤代-(C1-C6)-烷基，(C2-C6)-烷氧基烷基，甲酰基，(C2-C6)-烷基羰基，(C2-C6)-烷氧基羰基，C(O)NR26R27，(C1-C6)-烷基磺酰基，卤代-(C1-C6)-烷基磺酰基，或代表在苯环上被k个选自(C1-C3)-烷基，卤素，氰基和硝基的基团取代的苯基，苄基，苯甲酰基，CH2C(O)苯基或苯基磺酰基；R30是(C1-C6)-烷基或(C1-C6)-烷氧基；a是0，1，2，3或4；b是1或2；k是0，1，2或3；i是0，1或2；m是0或1；n是0或1；p是1，2或3；q是0，1或2；v是0，1，2，3，4或5；w是0，1，2或3，以及B)选自下列各组除草剂中一组的至少一种化合物(组分B)B-a)可选择性防除谷类作物中的单子叶和/或双子叶有害植物的除草剂，B-b)可选择性防除玉米中的单子叶和/或双子叶有害植物的除草剂，B-c)可选择性防除水稻中的单子叶和/或双子叶有害植物的除草剂，B-d)在未耕作土地上不具选择活性的除草剂和/或可选择性防除转基因作物中的单子叶和/或双子叶有害植物的除草剂，其中上述组合物中含有的式(I)化合物或它们的盐(组分A)与B-a)至B-d)组的化合物(组分B)之间的重量比为1∶2000至2000∶1。