[发明专利]一种手性（R）-α-苯乙胺铂配合物晶体

说明书

一、技术领域

本发明涉及一种金属有机配位化合物（配合物）及其制备方法，特别涉及含氧金属有机 配合物及其制备方法，确切地说是一种双(R)-α-苯乙胺氯化铂配合物晶体及其合成方法。

二、背景技术

金属铂配合物因其在抗癌和分子磁体、荧光材料等方面的潜在应用价值已引起人们的 广泛关注。金属铂配合物的合成方法近年来有许多文献报道。【1-7】

1.AComparativeAntimicrobialStudyInBetweenaQuinolineDrugandIts Complexes:Spectral,Kinetic,andMolecularModelingInvestigations,Al- Hazmi,GamilA.A.;Saad,FawazA.SynthesisandReactivityinInorganic, Metal-Organic,andNano-MetalChemistry(2015),45(11),1743-1757.

2.One-potsynthesisofdual-emittingBSA-Pt-Aubimetallicnanoclusters forfluorescenceratiometricdetectionofmercuryionsandcysteine,Ding, Shou-Nian;Guo,Yun-Xia

FromAnalyticalMethods(2015),7(14),5787-5793.

3.Fivecoordinateplatinum(II)in[Pt(bpy)(cod)(Me)][SbF6]:astructural andspectroscopicstudy,Klein,Axel;Neugebauer,Michael;Krest,Alexander; Luening,Anna;Garbe,Simon;Arefyeva,Natalia;Schloerer,Nils,Inorganics (2015),3(2),118-138.

4.SynthesisandReactivityofPlatinum(II)cis-Dialkyl,cis-Alkyl Chloro,andcis-AlkylHydridoBis-N-heterocyclicCarbeneChelateComplexes, Brendel,Matthias;Engelke,Rene;Desai,VidyaG.;Rominger,Frank;Hofmann, Peter,Organometallics(2015),34(12),2870-2878.

5.TheChallengeofDecipheringLinkageIsomersinMixturesofOligomeric ComplexesDerivedfrom9-Methyladenineandtrans-(NH3)2PtIIUnits,Ibanez, Susana;Mihaly,Bela;SanzMiguel,PabloJ.;Steinborn,Dirk;Pretzer,Irene; Hiller,Wolf;Lippert,Bernhard

Chemistry-AEuropeanJournal(2015),21(15),5794-5806.

6.Polypyridylrutheniumcomplexescontaininganchoringnitrilegroupsas TiO2sensitizersforapplicationinsolarcells,MecchiaOrtiz,JuanH.; Longo,Claudia;Katz,NestorE.InorganicChemistryCommunications(2015), 55,69-72.

7.Charge-bistablePd(III)/Pd(II,IV)coordinationpolymers:phase transitionsandtheirapplicationstoopticalproperties,Kumagai,Shohei; Takaishi,Shinya;Iguchi,Hiroaki;Yamashita,Masahiro,DaltonTransactions (2015),44(18),8590-8599。

三、发明内容