[发明专利]具有杀虫作用的取代的联苯基噁唑啉衍生物

说明书

本发明涉及新的取代的噁唑啉衍生物，其制备方法和其防治动物害虫的用途。

已知噁唑啉衍生物具有杀虫和杀螨活性(参见，例如EP-A-0432661,EP-A-696584,WO-A95/04726,WO-A96/11190或WO-A96/22283)，例如2-(2,6-二氟苯基)-4-(4’-甲氧基-或异丙氧基联苯-4-基)-1,3-噁唑啉(参见EP-A0432661)。

但是，这些已知化合物作用的效力和/或作用期，特别是抗某些有机体，或者在低施用浓度时，并不是在所有应用领域令人完全满意。

因此，本发明提供式(Ⅰ)新的取代的噁唑啉衍生物其中基团A,B,Q和R各自在下面的表1中定义：表1化合物序号  A    B    Q             R1           F    F    H    2           Cl   H    H    3           F    Cl   H    -CH₂-C(CH₃)=N-O-CH(CH₃)C₂H₅4           F    Cl   H    -C(CH₃)₂-C(CH₃)=N-O-C₃H₇-i5           Br   H    H    -C₃H₇-i6           F    F    H    -CO-NH-C₃H₇-i7           F    F    H    -CF=CF-CH=CH₂8           F    F    H    -CH₂-CH=NOCH₃9           H    Cl   H    -C₃H₇-n10          H    Cl   H    11          H    Cl   H    -C₃H₇-i表1(续)化合物序号   A    B     Q       R12           H    Cl    H    -C₄H₉-n13           H    Cl    H    14           H    Cl    H    -CH₂-C₃H₇-i15           F    F     H    -CH₂CH₂-CH=CF₂16           F    F     H    -CH₂-CH=NOC₂H₅17           F    F     H    18           F    F     H    19           F    F     H    20           F    F     H    21           F    F     H    22           I    H     H    23           F    F     H    24           F    F     H    25           F    F     H    26           F    F     H    表1(续)化合物序号   A    B     Q       R27           F    Cl    H    -C₃H₇-i28           F    F     H    29           F    Cl    H    -C₃H₇-n30           F    Cl    H    -CH₂-C₃H₇-i31           F    F     H    32           F    F     H    33           F    F     H    34           F    Cl    H    -C₄H₉-n35           F    F     H    -CH(CH₃)-CH=NOCH₃36           F    F     H    -CH(CH₃)-C≡CH37           Cl   H     H    -CH(CH₃)-C≡CH38           Cl   F     H    39           Cl   H     H    -CH₂-C₃H₇-i40           Cl   Cl    H    41           Cl   Cl    H    -C₃H₇-i42           F    F     H    表1(续)化合物序号   A    B    Q         R43           F    F    Cl   44           F    F    Cl   45           Cl   H    Cl   46           F    F    H    47           F    Cl   H    48           F    Cl   H    49           F    Cl   H    50           F    F    H    51           F    F    H    52           F    F    H    53           F    F    H    -C(CH₃)₂-CH=NOC₂H₅54           F    Cl   H    55           F    F    H    56           F    F    H    表1(续)化合物序号   A       B    Q            R57           F       F    H    -C(CH₃)₂-CH=NOCH₃58           Cl      H    H    59           F       F    H    60           F       F    H    61           Cl      H    Cl   62           Cl      H    Cl   63           F       F    Cl   64           F       F    Cl   65           Cl      Cl   H    -CH(CH₃)-COCH₃66           Cl      Cl   H    67           Cl      Cl   H    68           Br      H    H    -CH(CH₃)-COCH₃ 69           Cl      H    H         CF₃70         CH₃O-    H    H         CF₃71         CF₃      H    H         CF₃72         CH₃SO₂- H    H         CF₃73         C₂H₅O-  H    H         CF₃表1(续)化合物序号     A                    B                 Q      R74            i-C₃H₇O-           H                 H     CF₃75            NO₂                 H                 H     CF₃76            CH₃O-               F                 H     CF₃77            F                    NH₂              H     CF₃78            CH₃S-               H                 H     CF₃79            i-C₃H₇S-           H                 H     CF₃80            C₂H₅S-             H                 H     CF₃81            C₂H₅O-             F                 H     CF₃82            C₂H₅CH(CH₃)O-     F                 H     CF₃83            C₂H₅CH(CH₃)O-  C₂H₅CH(CH₃)O-    H     CF₃84            i-C₃H₇CH₂O-       F                 H     CF₃85            i-C₃H₇CH₂O-    i-C₃H₇CH₂O-      H     CF₃86            C₂H₅               H                 H     CF₃87                          H                 H     CF₃88            CH₃O                H                 H   C₃H₇-i89            Br                   H                 H     CF₃90            I                    H                 H     CF₃91            Br                   H                 H -CH(CH₃)-CH(OH)CH₃92            Br                   H                 H -CH(CH₃)-C(CH₃)=NOCH₃93            H                    H                 H     C₃H₇-i表1(续)化合物序号    A     B    Q        R94            I     H    H    95            Br    H    H    -CH₂-CH=CH₂96            Br    H    H    -CH₂-C≡CH97            F     H    Cl   98            F     H    Cl   99            F     Cl   H    100           F     H    H    -CH(CH₃)-COCH₃101           F     H    H    102           F     F    H    -C(CH₃)₂-CHO103           F     H    Cl   104           F     Cl   H    表1(续)化合物序号     A    B    Q      R105            F    H    Cl   106            F    H    Cl   107            F    H    H    -C₃H₇-i108            F    H    H    -CH₂-C₃H₇-i109            F    H    H    110            F    H    H    111            F    H    H    112            F    Cl   H     -CH₂-CH=NOCH₃113            F    Cl   H     -CH₂-CH=NOC₂H₅114            F    F    Cl    -CH₂-CH=NOCH₃115            F    F    Cl    -CH₂-CH=NOC₂H₅116            Cl   H    Cl    -CH₂-CH=NOCH₃117            Cl   H    Cl    -CH₂-CH=NOC₂H₅118            F    H    Cl    -CH₂CF₃119            F    F    CH₃  -CH₂CF₃120    CF₃CH₂O-  F    CH₃  -CH₂CF₃表1(续)化合物序号      A    B     Q          R121             Cl   H   -CH₂-  -CH₂CF₃                         CH=CH₂    122             Cl   H   CH₃    -CH₂CF₃123             F    F   C₂H₅  CH₂CF₃124             Cl   H     H     -CH₂CF₃125             F    F     H     126             F    F     H     -CH₂-CF₂-CHF₂127             F    F     H     -(CH₂)₃-CF₂-CF₃