[发明专利]具有杀虫作用的取代的联苯基噁唑啉衍生物

摘要

本发明涉及式(Ⅰ)的新的噁唑啉衍生物,其中基团A,B,Q和R具有说明书中给出的定义。本发明还涉及它们的制备方法和它们在害虫防治中的用途。

主权项

1．式(Ⅰ)的化合物1至127其中基团A,B,Q和R各自在下面的表1中定义：表1化合物序号   A    B   Q                R1            F    F   H2            Cl   H   H3            F    Cl  H    -CH2-C(CH3)=N-O-CH(CH3)C2H54            F    Cl  H    -C(CH3)2-C(CH3)=N-O-C3H7-i5            Br   H   H    -C3H7-i6            F    F   H    -CO-NH-C3H7-i7            F    F   H    -CF=CF-CH=CH28            F    F   H    -CH2-CH=NOCH39            H    Cl  H    -C3H7-n10           H    Cl  H11           H    Cl  H    -C3H7-i表1(续)化合物序号    A    B    Q       R12            H    Cl   H    -C4H9-n13            H    Cl   H14            H    Cl   H    -CH2-C3H7-i15            F    F    H    -CH2CH2-CH=CF216            F    F    H    -CH2-CH=NOC2H517            F    F    H18            F    F    H19            F    F    H20            F    F    H21            F    F    H22            I    H    H23            F    F    H24            F    F    H25            F    F    H26            F    F    H表1(续)化合物序号    A    B     Q       R27            F    Cl    H    -C3H7-i28            F    F     H29            F    Cl    H    -C3H7-n30            F    Cl    H    -CH2-C3H7-i31            F    F     H32            F    F     H33            F    F     H34            F    Cl    H    -C4H9-n35            F    F     H    -CH(CH3)-CH=NOCH336            F    F     H    -CH(CH3)-C≡CH37            Cl   H     H    -CH(CH3)-C≡CH38            Cl   F     H39            Cl   H     H    -CH2-C3H7-i40            Cl   Cl    H41            Cl   Cl    H    -C3H7-i42            F    F     H表1(续)化合物序号    A    B    Q         R43            F    F    Cl44            F    F    Cl45            Cl   H    Cl46            F    F    H47            F    Cl   H48            F    Cl   H49            F    Cl   H50            F    F    H51            F    F    H52            F    F    H53            F    F    H     -C(CH3)2-CH=NOC2H554            F    Cl   H55            F    F    H56            F    F    H表1(续)化合物序号    A      B    Q            R57            F      F    H    -C(CH3)2-CH=NOCH358            Cl     H    H59            F      F    H60            F      F    H61            Cl     H    Cl62            Cl     H    Cl63            F      F    Cl64            F      F    Cl65            Cl     Cl   H    -CH(CH3)-COCH366            Cl     Cl   H67            Cl     Cl   H68            Br     H    H    -CH(CH3)-COCH369            Cl     H    H         CF370         CH3O-    H    H         CF371         CF3      H    H         CF372         CH3SO2- H    H         CF373         C2H5O-  H    H         CF3表1(续)化合物序号      A               B                Q     R74          i-C3H7O-         H                H    CF375            NO2             H                H    CF376            CH3O-           F                H    CF377             F               NH2             H    CF378            CH3S-           H                H    CF379           i-C3H7S-        H                H    CF380            C2H5S-         H                H    CF38l            C2H5O-         F                H    CF382         C2H5CH(CH3)O-    F                H    CF383         C2H5CH(CH3)O-  C2H5CH(CH3)O-   H    CF384         i-C3H7CH2O-      F                H    CF385         i-C3H7CH2O-    i-C3H7CH2O-     H    CF386             C2H5          H                H    CF387H                H    CF388             CH3O           H                H    C3H7-i89              Br             H                H    CF390              I              H                H    CF391              Br             H                H -CH(CH3)-CH(OH)CH392              Br             H                H -CH(CH3)-C(CH3)=NOCH393              I              H                H    C3H7-i表1(续)化合物序号     A    B    Q        R94             I    H    H95             Br   H    H    -CH2-CH=CH296             Br   H    H    -CH2-C≡CH97             F    H    Cl98             F    H    Cl99             F    Cl   H100            F    H    H    -CH(CH3)-COCH3101            F    H    H102            F    F    H    -C(CH3)2-CHO103            F    H    Cl104            F    Cl   H表1(续)化合物序号    A    B    Q      R105           F    H    Cl106           F    H    Cl107           F    H    H    -C3H7-i108           F    H    H    -CH2-C3H7-i109           F    H    H110           F    H    H111           F    H    H112           F    Cl   H     -CH2-CH=NOCH3113           F    Cl   H     -CH2-CH=NOC2H5114           F    F    Cl    -CH2-CH=NOCH3115           F    F    Cl    -CH2-CH=NOC2H5116           Cl   H    C1    -CH2-CH=NOCH3117           Cl   H    Cl    -CH2-CH=NOC2H5118           F    H    Cl    -CH2CF3119           F    F    CH3  -CH2CF3120     CF3CH2O- F    CH3  -CH2CF3表1(续)化合物序号      A     B        Q            R121            Cl    H   -CH2-CH=CH2  -CH2CF3122            Cl    H       CH3       -CH2CF3123            F     F       C2H5     CH2CF3124            Cl    H         H        -CH2CF3125            F     F         H126            F     F         H        -CH2-CF2-CHF2127            F     F         H        -(CH2)3-CF2-CF3。